Enhancement of bimetallic Fe-Mn/CNTs nano catalyst activity and product selectivity using microemulsion technique

Abstract

Bimetallic Fe-Mn nano catalysts supported on carbon nanotubes (CNTs) were prepared using microemulsion technique with water-to-surfactant ratios of 0.4–1.6. The nano catalysts were extensively characterized by different methods and their activity and selectivity in Fischer-Tropsch synthesis (FTS) have been assessed in a fixed-bed microreactor. The physicochemical properties and performance of the nanocatalysts were compared with the catalyst prepared by impregnation method. Very narrow particle size distribution has been produced by the microemulsion technique at relatively high loading of active metal. TEM images showed that small metal nano particles in the range of 3–7 nm were not only confined inside the CNTs but also located on the outer surface of the CNTs. Using microemulsion technique with water to surfactant ratio of 0.4 decreased the average iron particle sizes to 5.1 nm. The reduction percentage and dispersion percentage were almost doubled. Activity and selectivity were found to be dependent on the catalyst preparation method and average iron particle size. CO conversion and FTS rate increased from 49.1% to 71.0% and 0.144 to 0.289 gHC/(gcat·h), respectively. While the WGS rate decreased from 0.097 to 0.056 gCO2/(gcat·h). C5+ liquid hydrocarbons selectivity decreased slightly and olefins selectivity almost doubled.