Enhancement of anaerobic digestion of waste activated sludge by alkaline solubilization

Abstract

The performance of an anaerobic digestion fed with waste activated sludge (WAS) pretreated with NaOH was examined. The sludge was periodically collected from a municipal wastewater-treatment plant. The laboratory work was run in four 1-l semi-continuous anaerobic digestion reactors. Reactor A was fed with untreated WAS at 1% total solids (TS). The other three reactors, B, C and D, were respectively fed with WAS (1% TS) pretreated with 20 meq/l NaOH, WAS (1% TS) pretreated with 40 meq/l NaOH, and WAS (2% TS) pretreated with 20 meq/l NaOH. The reactors were operated at 35°C at four hydraulic retention times — 20, 13, 10 and 7.5 days. The performances of reactors B, C and D, in terms of chemical oxygen demand (COD), volatile solids (VS) removal, and gas production, were superior to that of reactor A. At a retention time of 10 days, the COD removals of reactors A, B, C and D were 38, 46, 51 and 52%, respectively. The gas productions of reactors B, C and D were, respectively, increased by 33, 30 and 163% over that of reactor A. The sludge dewaterability was examined by capillary suction time (CST). The dewaterability of digested sludge was improved in reactors B, C and D. Capillary suction of digested sludges gave times in the range 148–389 s, compared with 309–735 s for undigested sludges.