Enhancement of acoustic properties of carbon fibrous membrane (CFM) by in-situ crystallization of PZT nanogenerators (PENGs) inside the fibers for a low-frequency acoustic energy harvesting

Abstract

Acoustic energy harvesting (AEH) by a nanostructured membrane has recently gained increasing attention. This study focused on a novel approach for in-situ crystallization of Pb(Zr0.58Ti0.42)O3 (PZT) as a piezoelectric nanogenerator (PENG) inside the carbon fibrous membranes (CFM). The electrospinning process and post-heat treatment were applied to synthesize the CFM-embedded PENG, which benefits from both the flexibility of carbon fibers and the piezoelectric properties of the crystallized PZT. The results indicated that the carbon fibers kept their microstructure over the heat treatment at 250 and 350 °C while the crystallization fraction of PZT increased. The XPS analysis revealed that the CFM embedded by in-situ crystallized PENG had a higher diversity of tetragonal and rhombohedral in comparison with the CFM embedded by the pre-crystallized PENGs. Furthermore, the electrical conductivity, dielectric constant, and ferromagnetic properties of CFM were improved with the incorporation of the in-situ crystallized PENGs. The acoustic studies in the range of 250–2000 Hz under sound pressure of 90 dB revealed that sound absorption performance of CFM was increased by about +35 %. Also, the ability of CFM in the AEH process was enhanced drastically by embedding the PENGs inside the carbon fibers. The maximum harvested electricity at 500 Hz was 5.9 and 13.9 W m−2 by CFM embedded by in-situ crystallized and pre-crystallized PENGs, respectively. The above results exhibit the great potential for the CFM-embedded PENGs to be used in low-frequency AEH applications.