Enhancement in the Structural, Electrical, Optical, and Photocatalytic Properties of La2O3-Doped ZnO Nanostructures.

Abstract

A lanthanum oxide (La2O3)-ZnO nanostructured material was synthesized in the proposed study with different La2O3 concentrations, 0.001 g to 5 g (named So to S7), using the combustion method. X-ray diffraction (XRD), scanning electron microscopy (SEM), and Fourier transformation infrared spectroscopy (FT-IR) were utilized for investigating the structure, morphology, and spectral studies of the La2O3- ZnO nanomaterials, respectively. The results obtained from previous techniques support ZnO’s growth from crystalline to nanoparticles’ fine structure by changing the concentrations of lanthanum oxide (La2O3) dopants in the host matrix. The percentage of ZnO doped with La- influences the ZnO photocatalytic activity. SEM analysis confirmed the grain size ranged between 81 and 138 nm. Furthermore, UV-Vis diffuse reflectance spectroscopy was performed to verify the effects of La2O3 dopants on the linear optical properties of the nano-composite oxides. There was a variation in the energy bandgaps of La2O3-ZnO nanocomposites, increasing the weight concentrations of lanthanum dopants. The AC electrical conductivity, dielectric properties, and current–voltage properties support the enactment of the electrical characteristics of the ZnO nanoparticles by adding La2O3. All the samples under investigation were used for photodegradation with Rhodamine B (RhB) and Methylene Blue (MB). In less than 30 min of visible light irradiation, S4 (0.5 g) La2O3-ZnO reached 99% of RhB and MB degradation activity. This study showed the best photocatalytic effect for RhB and MB degradation of 0.13 and 0.11 min−1 by 0.5 g La2O3-ZnO. Recycling was performed five times for the nanocatalysts that displayed up to 98 percent catalytic efficiency for RhB and MB degradation in 30 min. The prepared La2O3-ZnO nanostructured composites are considered novel candidates for various applications in biomedical and photocatalytic studies.