Abstract
Zinc antimonide (ZnSb) is a promising thermoelectric material due to its economic viability, elemental abundance, and superior phase stability compared to other Zn-Sb compounds. However, its widespread application is hindered by a low figure-of-merit (zT). Extensive research has explored doping, alloying, and nanostructuring to improve zT. This study investigates the impact of Cr doping in CryZn1-ySb (y = 0.0 – 0.03). Cr doping with y = 0.01 significantly reduces lattice thermal conductivity below the phonon glass limit. Debye-Callaway model calculations suggest a combined effect of point defects and decreased grain size caused by Cr incorporation. This reduction translates to enhanced thermoelectric performance, with the y = 0.01 sample exhibiting a 70 % improvement in zT at 673 K, reaching ∼0.67. Exceeding the Cr substitution limit leads to the formation of a detrimental secondary CrSb2 phase, increasing thermal conductivity. The Single Parabolic Band model calculations predict further zT enhancement in y = 0.01 sample to ∼0.2 at 300 K through optimized carrier concentration (307 % improvement in zT). These findings demonstrate the potential for significant zT improvement in ZnSb via defect engineering and carrier concentration tuning.
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