Enhanced thermal storage and photo-thermal conversion composite phase change materials based on MOF-derived carbon for efficient solar energy utilization

Abstract

Composite phase change materials (PCMs) with high thermal conductivity and photo-thermal conversion performance can be employed for the efficient conversion and utilization of solar energy. In this work, a Ni-doped carbon material derived from a Ni metal-organic framework (Ni-BTC) is prepared and used as the supporting material to encapsulate polyethylene glycol (PEG). The Ni-BTC derived carbon (NBC) obtained retained the intrinsic porous flower-like structure which facilitates the encapsulation of PEG. The doping of Ni metal particles enhances both the thermal conductivity and photo-thermal conversion performance of the composite PCM. Additionally, the thermal conductivity of the composite PCM is further enhanced by the addition of a graphene/Ag composite, resulting in a thermal conductivity that is 3.15 times higher than that of pure PEG. The latent heat of the resulting composite PCM is 125.4 J/g, the photo-thermal conversion efficiency is 91.81 %. Moreover, the composite PCM exhibits excellent thermal stability and reliability, indicating its potential for wide-ranging applications in solar energy storage.