Abstract
Despite their low specific surface area (<500 m2 g−1) relative to that of activated carbon (1500–2000 m2 g−1), carbon nanotubes are attractive as effective electrode materials for supercapacitors. Electrodes comprised of arrays of helically coiled carbon nanotubes (HCNTs) and multi-wall carbon nanotubes (MWCNTs) were prepared and evaluated as novel electrode materials for electric double layer capacitors (EDLCs). While both types of electrodes exhibited a linear dependence on array height and a diffusion limited behavior below the 1 V s−1 scan rate, the electrodes comprised of HCNT arrays exhibited better performance. Freestanding HCNT and MWCNT buckypapers were also prepared and used as electrodes, and the former showed a higher energy density relative to the latter with no loss in its power density and capacity fade. Collectively, this study concludes that HCNTs are well suited as binder-free electrodes that can be augmented with electroactive polymers for improved EDLC performance.
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