Enhanced removal of Eriochrome Black T from water using biochar/layered double hydroxide/chitosan hybrid composite: Performance evaluation and optimization using BBD-RSM approach

Abstract

In this research work, a novel hybrid composite consisting of biochar (B), layered double hydroxide (CuFe) and chitosan (CS) (B-CuFe-CS) was produced using an ultrasonication-assisted co-precipitation method. The resultant composite was employed for adsorptive removal of Eriochrome black T (EBT) from water. Physicochemical characterization indicated that the B-CuFe-CS containing 10 wt % CS exhibited a heterogeneous structure with better crystallographic and textural characteristics. The B-CuFe-CS with abundant surface functionalities (-CO, -C-O, –OH, –NO3, and MMO), facilitates faster and enhanced removal of the EBT. The kinetic results showed better fitting to the pseudo-second order model, and equilibrium was achieved within 30 min. Equilibrium data was well explained by Langmuir and Redlich Peterson isotherm models (R2 > 0.98), indicating the EBT removal onto B-CuFe-CS followed monolayer adsorption. The maximum adsorption capacity was 806.4 mg/g, which was higher than pristine B–CuFe (476.19 mg/g) and many other adsorbents. The spectroscopic analysis (FTIR and XPS) and experimental results suggested that EBT adsorption is mainly governed by electrostatic, chemical and anion-exchange interactions. It is evident from these results that coupling B–CuFe composite with bio-filler (chitosan) resulted in an efficient bio-adsorbent to effectively purify dye-contaminated water streams.