Enhanced properties of gelatin films incorporated with TiO2-loaded reduced graphene oxide aerogel microspheres for active food packaging applications

Abstract

The synergistic effect of graphene sheets and titanium dioxide nanoparticles (TiO2) hybrid fillers can improve the antibacterial, mechanical, and barrier properties of gelatin (GL), making it more suitable to be used in the food packaging application. However, the uneven dispersion and aggregation of the hybrid fillers restrict its performance for further application. In order to achieve the above superior properties, reduced graphene oxide aerogel microspheres (rGOAMs) loaded with TiO2 (rGOAMs@TiO2) were successfully prepared using one-step hydrothermal process by reducing titanium sulfate into TiO2 on the framework of rGOAMs, followed by effective dispersion in the GL matrix to form nanocomposites (rGOAMs@TiO2/GL) through simultaneous ultrasonication and mechanical stirring, as well as an ultrasonic cell grinder process. Incorporating a mere 0.8 wt% of rGOAMs@TiO2 effectively improved the mechanical, antibacterial, UV light barrier, thermal stability, hydrophobicity, and water vapor barrier properties of the GL. Compared with the composites made of rGOAMs, TiO2, and GL (rGOAMs/TiO2/GL), rGOAMs@TiO2/GL composites showed stronger filler-matrix interactions, better filler dispersion, and lower TiO2 particle aggregation, suggesting superiority compared to rGOAMs/TiO2/GL composites at the same filler content. This innovative method of mixing GL with rGOAMs@TiO2 holds great promise for enhancing the suitability of GL in active food packaging applications.