Enhanced photoelectrochemical water splitting in hierarchical porous ZnO/Reduced graphene oxide nanocomposite synthesized by sol-gel method

Abstract

Today the utilization of solar energy to split water and its conversion to hydrogen and oxygen has been considered as a powerful way to solve the environmental crisis. Hierarchical porous nanostructured ZnO and ZnO/reduced graphene oxide (rGO) composite photoanodes are synthesized by innovated sol-gel method using triethylenetetramine (TETA) as a stabilizer. The hierarchical porous ZnO structure containing large agglomerates each consisting of tiny nanoparticles are formed. The X-ray diffraction analysis and Raman spectroscopy confirm the in-situ reduction of graphene oxide sheets during synthesis and formation of ZnO/rGO nanocomposite. Although the band gap and transmittance of the porous nanocomposites do not dramatically change by rGO addition, the main photoluminescence peak quenches entirely showing prolonging exciton lifetime. The ZnO/rGO porous structure achieved remarkably improved current density (1.02 mA cm−2 at 1.5 V vs. Ag/AgCl) in 1 wt% rGO, up to 12 times higher compared to the bare ZnO (0.09 mA cm−2 at 1.5 V vs. Ag/AgCl), which attributes to positive role of ZnO hierarchical porous structure and rGO electron separation/transportation. These findings provide new insights into the broad applicability of this methodology for promising future semiconductor/graphene composite in the field of photoelectrochemical water splitting.