Enhanced photocatalytic degradation of tetracycline using NiCo–BiVO4 nanocomposite under visible light irradiation: A noble-metal-free approach for water remediation

Abstract

The increasing pollution of water bodies with organic contaminants, including antibiotics, has become a significant environmental concern. In this study, a noble-metal-free alternative, NiCo bimetal cocatalyst, was synthesized and applied to enhance the photocatalytic degradation of the antibiotic tetracycline (TC) using BiVO4 as the photocatalyst under the visible spectrum. The NiCo–BiVO4 nanocomposite exhibited improved visible light absorption, reduced recombination rate of charge carriers, and enhanced electrochemical properties. The photocatalytic degradation of TC was significantly enhanced by the NiCo bimetal modification, with the 2 wt% NiCo–BiVO4 nanocomposite achieving an 87.2% degradation of TC and 82% Total Organic Carbon (TOC) removal within 120 min. The degradation kinetics of TC (target compound) followed a first-order reaction, with photogenerated electrons and holes identified as the primary active species responsible for the degradation process. The recyclability of the catalyst was also demonstrated for multiple runs, indicating its stability. Furthermore, the pathway of TC degradation by 2 wt% NiCo–BiVO4 nanocomposite was proposed based on the detected intermediate products using LC-MS analysis. This study provides a promising approach for developing efficient, noble-metal-free photocatalysts to remove organic contaminants from water sources.