Enhanced Photocatalytic Degradation of Methylene Blue Using Ti-Doped ZnO Nanoparticles Synthesized by Rapid Combustion.

Abstract

ZnO and Ti-doped ZnO (Ti-ZnO) nanoparticles were synthesized using rapid combustion. The morphology of ZnO and Ti-ZnO featured nanoparticles within cluster-like structures. The ZnO and Ti-ZnO structures exhibited similar hexagonal wurtzite structures and crystal sizes. This behavior occurred because Zn2+ sites of the ZnO lattice were substituted by Ti4+ ions. The chemical structure characterization implied the major vibration of the ZnO structure. The physisorption analysis showed similar mesoporous and non-rigid aggregation structures for ZnO and Ti-ZnO using N2 adsorption-desorption. However, Ti-ZnO demonstrated a specific surface area two times higher than that of ZnO. This was a major factor in improving the photocatalytic degradation of methylene blue (MB). The photocatalytic degradation analysis showed a kinetic degradation rate constant of 2.54 × 10-3 min-1 for Ti-ZnO, which was almost 80% higher than that of ZnO (1.40 × 10-3 min-1). The transformation mechanism of MB molecules into other products, including carbon dioxide, aldehyde, and sulfate ions, was also examined.