Enhanced performance of novel carbon nanotubes - sulfonated poly ether ether ketone (speek) composite proton exchange membrane in mfc application

Abstract

Sulfonated poly ether ether ketone (SPEEK) nanocomposite proton exchange membrane (PEM) was prepared by incorporating multi-walled carbon nanotubes (CNT) at different weight percentages for microbial fuel cell (MFC) applications. Physico-chemical, thermal, mechanical and morphological characteristics of the prepared CNT-SPEEK composite membranes were analyzed using various techniques. Further, the water uptake capacity, Ion exchange capacity (IEC) and MFC performance of the CNT-SPEEK composite membranes were evaluated and compared with the pristine SPEEK membrane. Results show that incorporation of CNTs in SPEEK membranes exhibited a better water uptake capacity (34.18%–36.02%) and IEC (1.94–2.15 meq/g) compared to the SPEEK membrane. Improvement in membrane properties resulted in 2-fold higher power density compared to SPEEK membrane. Composite membrane with 0.75% CNT-SPEEK produced the higher power density (1.77 W/m2) in comparison with all the membranes evaluated. Chemical oxygen demand (COD) removal efficiency values of the MFC with SPEEK composite membranes were also found to be around 90%. Overall, the results reveal that CNT-SPEEK composite membrane as a potential PEM for MFC applications.