Enhanced micro-explosion to improve the yield of light oil in catalytic cracking of water-in-heavy oil emulsion prepared by continuous membrane emulsification

Abstract

Membrane emulsification provides new ideas for improving the atomization performance of high viscosity heavy oil in catalytic cracking process, thereby improving the distribution of catalytic cracking products. A comprehensive understanding of the micro-explosion characteristics and catalytic cracking of low water content heavy oil emulsion is the key to the application of membrane emulsification technology in heavy oil catalytic cracking process. Therefore, different water droplet sizes and water content of heavy oil emulsion were controllably prepared by continuous membrane emulsification, and their micro-explosion characteristics and catalytic cracking performance were investigated. The evaporation of heavy oil emulsion droplets (water content over 3 vol%) only underwent the heat transfer stage and the fluctuating evaporation stage due to the strong micro-explosion. The micro-explosion delay time of emulsion droplets decreased from 2.631 to 0.434 s/mm2 with increased temperature (300–600 ℃), increased from 0.645 to 1.042 s/mm2 with increased water content (1–5 vol%), and increased from 0.642 to 1.237 s/mm2 with increased average droplet size (1.80–14.6 μm). The child droplets generated after micro-explosion were characterized, and the different heating behaviors were quantitatively distinguished by the average size of the child droplets. Additionally, the micro-explosion performance (i.e. child droplets size and strong micro-explosion probability) of emulsion droplets improved with increasing water content and average water droplet size, while it initially decreased and then increased when the temperature increased. Furthermore, the improvement of micro-explosion performance by membrane emulsification can increase the yield of light oil (up to a maximum increase of 10.82 %) and reduce the yield of coke (up to a maximum decrease of 5.99 %) in the heavy oil emulsion catalytic cracking.