Enhanced Mechanical Properties of Yellow ZrN Ceramic with Addition of Solid Solution of TiN

Abstract

As a superhard ceramic with a yellow color and excellent electrical conductivity, ZrN has potential applications in the field of decoration, but it is limited by its poor mechanical properties. In this work, the mechanical properties of ZrN ceramic were improved by forming a (Zr, Ti)N solid solution via spark plasma sintering of a ZrN and TiN powder mixture. The influences of the amount of TiN additive on the sinterability, microstructure, color, and mechanical properties of ZrN ceramic were investigated. X-ray diffraction analysis, energy-dispersive spectroscopy, and microstructural images indicated that Ti atoms dissolved into a ZrN lattice, and a (Zr, Ti)N solid solution was formed during the sintering process. When the content of TiN was 10 vol%, the obtained (Zr, Ti)N composite exhibited the best comprehensive mechanical properties; the Vickers hardness, flexural strength, and fracture toughness were 15.17 GPa, 520 MPa, and 6.03 MPa·m1/2, respectively. The color coordinates and color temperature diagram revealed the addition of TiN hardly impacted the color performance of the ZrN ceramic.