Enhanced mechanical properties of R–SiC honeycomb ceramics with in situ AlN–SiC solid solution

Abstract

Recrystallized SiC (R–SiC) honeycomb ceramics were prepared using Al4SiC4 as additives through a two–step sintering process, consisting of pre–nitridation treatment at 1800 °C for 180 min, followed by heat treatment for 60 min at temperatures ranging from 2000 to 2200 °C. The influences of firing temperature on phase compositions, microstructures, porosity, and mechanical properties of honeycomb ceramics were evaluated. The results revealed that AlN, SiC, and C were formed in situ after nitriding at 1800 °C. As the subsequent heat treatment temperature increased from 2000 to 2200 °C, the sublimation rate of submicron SiC increased, as well as AlN solid solubility. AlN diffused into SiC lattice and formed the SiC–AlN solid solution, which accelerated the conversion of 6H–SiC to 4H–SiC. According to first–principles calculations, the formation of solid solution contributed to the sintering process, which performed through the reduction of the surface energy of the grains. In addition, the pore size of specimens increased with elevating the heating temperature, and the distribution transitioned from unimodal to bimodal. Simultaneously, AlN and C activated the SiC lattice and facilitated mass transfer rate. The SiC sintering necks were well–developed at 2200 °C, resulting in the optimized overall performance of SiC honeycomb ceramics with a porosity of 52.7% and compressive strength of 17.98 MPa.