Abstract

Large magnetostrain can be demonstrated in Ni-Mn-X (X = In, Sn, Sb) meta-magnetic shape memory alloys by resuming the predeformed martensite through magnetic-field-induced reverse martensitic transformation. However, owing to the constraint from the self-accommodated microstructure and randomly distributed crystallographic orientation, spontaneous magnetostrain without predeformation in polycrystalline alloys remains low. Here, by combining microstructure texturing and superelastic training, enhanced spontaneous magnetostrain was achieved in a directionally solidified Ni44.5Co4.9Mn37.5In13.1 alloy with strong <0 0 1>A preferred orientation. After superelastic training through cyclic compressive loading/unloading on the directionally solidified alloy, a large spontaneous magnetostrain of ~0.65% was obtained by applying a magnetic field of 5 T, showing great improvement when compared to that of the untrained situation, i.e., ~0.45%. Such enhanced magnetoresponse is attributed to the internal stress generated through superelastic training, which affects the variant distribution and the resultant output strain in association with the martensitic transformation.

Highlights

  • IntroductionHeusler-type Ni-Mn-X (X = In, Sn, Sb) intermetallic compounds have received increasing attention in the past two decades, because various functional behaviors linked with the martensitic transformation in these compounds, e.g., magnetic shape memory effect [1–6], magnetocaloric effect [7–12], elastocaloric effect [13–18] and magnetoresistance effect [19,20], have potential applications in areas including actuation, sensing and solid-state refrigeration

  • The shape change caused by the deformation of martensite can be resumed on account of the reverse martensitic transformation induced by the magnetic field [1], giving rise to a one-way magnetic shape memory effect

  • The martensitic transformation was driven to much lower temperature range when the magnetic field of 5 T is applied, i.e., Ms = 242 K, Mf = 231 K, As = 250 K and Af = 261 K, suggesting that the magnetic field could be employed to drive the reverse martensitic transformation [1]

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Summary

Introduction

Heusler-type Ni-Mn-X (X = In, Sn, Sb) intermetallic compounds have received increasing attention in the past two decades, because various functional behaviors linked with the martensitic transformation in these compounds, e.g., magnetic shape memory effect [1–6], magnetocaloric effect [7–12], elastocaloric effect [13–18] and magnetoresistance effect [19,20], have potential applications in areas including actuation, sensing and solid-state refrigeration. These alloys are referred as meta-magnetic shape memory alloys, with the austenite in a ferromagnetic state and the martensite in a weak magnetic (anti-ferromagnetic or paramagnetic) state [1]. A reversible or two-way magnetic shape memory effect can be expected

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