Abstract
Large magnetostrain can be demonstrated in Ni-Mn-X (X = In, Sn, Sb) meta-magnetic shape memory alloys by resuming the predeformed martensite through magnetic-field-induced reverse martensitic transformation. However, owing to the constraint from the self-accommodated microstructure and randomly distributed crystallographic orientation, spontaneous magnetostrain without predeformation in polycrystalline alloys remains low. Here, by combining microstructure texturing and superelastic training, enhanced spontaneous magnetostrain was achieved in a directionally solidified Ni44.5Co4.9Mn37.5In13.1 alloy with strong <0 0 1>A preferred orientation. After superelastic training through cyclic compressive loading/unloading on the directionally solidified alloy, a large spontaneous magnetostrain of ~0.65% was obtained by applying a magnetic field of 5 T, showing great improvement when compared to that of the untrained situation, i.e., ~0.45%. Such enhanced magnetoresponse is attributed to the internal stress generated through superelastic training, which affects the variant distribution and the resultant output strain in association with the martensitic transformation.
Highlights
IntroductionHeusler-type Ni-Mn-X (X = In, Sn, Sb) intermetallic compounds have received increasing attention in the past two decades, because various functional behaviors linked with the martensitic transformation in these compounds, e.g., magnetic shape memory effect [1–6], magnetocaloric effect [7–12], elastocaloric effect [13–18] and magnetoresistance effect [19,20], have potential applications in areas including actuation, sensing and solid-state refrigeration
The shape change caused by the deformation of martensite can be resumed on account of the reverse martensitic transformation induced by the magnetic field [1], giving rise to a one-way magnetic shape memory effect
The martensitic transformation was driven to much lower temperature range when the magnetic field of 5 T is applied, i.e., Ms = 242 K, Mf = 231 K, As = 250 K and Af = 261 K, suggesting that the magnetic field could be employed to drive the reverse martensitic transformation [1]
Summary
Heusler-type Ni-Mn-X (X = In, Sn, Sb) intermetallic compounds have received increasing attention in the past two decades, because various functional behaviors linked with the martensitic transformation in these compounds, e.g., magnetic shape memory effect [1–6], magnetocaloric effect [7–12], elastocaloric effect [13–18] and magnetoresistance effect [19,20], have potential applications in areas including actuation, sensing and solid-state refrigeration. These alloys are referred as meta-magnetic shape memory alloys, with the austenite in a ferromagnetic state and the martensite in a weak magnetic (anti-ferromagnetic or paramagnetic) state [1]. A reversible or two-way magnetic shape memory effect can be expected
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