Enhanced Ionic Current Rectification through Innovative Integration of Polyelectrolyte Bilayers and Charged-Wall Smart Nanochannels

Abstract

The tools utilized by humans continue to shrink and speed up. Lab-on-a-chip (LOC) is one of the most recent techniques for decreasing the size of chemical systems. Today, LOCs have made substantial strides in developing nanomaterial fabrication techniques. Controlling and regulating the fluid and ion mobility in these systems is crucial. Layer-by-layer (LBL) soft layers are one of the most effective strategies for controlling fluid flow in channels. In light of the present constraints for developing these systems and the high expense of experimental investigations, it is vital to employ modeling to minimize costs and comprehend their underlying ideas and operations. In this study, we examined the influence of the LBL soft layer's presence in the charged nanochannels on the ion transport parameters. To examine the effect of the coating length of the LBL soft layer, we first examined three lengths of coating: one with a length greater than half (type (I)), one with a length equal to half (type (II)), and one with a length less than half (type (III)) of the nanochannel length. Then, by solving Poisson-Nernst-Planck and Navier-Stokes equations, we determined the influences of pH, soft layer charge density (NPEL/NA), bulk concentration (C0), and hard surface charge density (σ) on the ionic current rectification (Rf) and selectivity (S) of the nanochannel. The maximum rectification of 30.65 was achieved using a nanochannel of type (III) and σ = +10 mC/m2. The current results demonstrate a promising hybrid architecture consisting of an LBL soft layer and a smart charged nanochannel for enhanced rectification.