Abstract
Novel porous hollow carbon nanospheres (HCNS) have been synthesized and utilized as scaffold for LiBH4–Mg(BH4)2 eutectic borohydride (LMBH). Large loading amounts of LMBH (33, 50 and 67 wt%) have been melt-infiltrated into HCNS, and the significantly improved dehydrogenation properties have been discovered. The LMBH@HCNS composites not only exhibit high actual dehydrogenation amounts and fast hydrogen desorption rates, but also an increased reversible hydrogen storage capacities after three cycles without obvious degradation. Further structural tests have revealed that the over-infiltrated LMBH covering the spherical surface of HCNS could also contribute to the improved hydrogen storage behaviors, due to a strong interfacial adhesion effect that avoid LMBH from aggregation during de/rehydrogenation cycles.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
