Enhanced green up/down-conversion emissions through phase transformation in Ho3+/Yb3+ co-doped Y2O3:ZrO2 phosphors in presence of Na+ ions

Abstract

This study reports the intense green upconversion and downconversion emissions from Ho3+/Yb3+/Na+ co-doped Y2O3:ZrO2 phosphor prepared by traditional solid-state reaction technique for fixed concentration of Ho3+/Yb3+ ions and different concentrations of Na+ ion. The phosphor samples exhibit a multiphase crystalline structure in the absence of Na+ ions. However, with co-doping of Na+ ions (at 20 mol%), it almost turns into Y4Zr3O12 with single rhombohedral phase. When Na + ions are present in the sample, the SEM image reveals a growth in particle size. The UV–Vis–NIR measurements show an enhancement in the absorbance of doped REs ions (Ho3+/Yb3+) on Na+ co-doping. The Ho3+/Yb3+ co-doped Y2O3:ZrO2 phosphor shows an intense green upconversion (UC) emission at 549 nm due to Ho3+ ions on the excitation with 980 nm radiation. In the presence of Na + ions, a modification of the crystallinity, growth in crystallite size (particle size) and an increase in the asymmetry of the crystalline structure around the REs ions led to an enhancement in the intensity of the UC emission almost about ∼8.5 times. The Log-Log plot demonstrates the involvement of two photons in the UC process. The lifetime of the 5F4/5S2 level decreases with increasing the concentration of Na + ion. Thus, the prepared phosphor could be an excellent candidate for source of green light, finger printing, optoelectronic devices etc.