Abstract

In situ CeB6/Al composite has been proven to be an effective refiner for commercial pure aluminum, however, it remains unclear as to the mechanisms of synthesis and grain refinement. We use low-temperature alloying and high-speed melt spinning to optimize the microstructure of CeB6. It is found that in situ CeB6/Al composite shows controllable microstructure and its refining effect is obviously dependent on the size of CeB6 particle/cluster. As nano-CeB6 particles self-assemble into submicron clusters, the inoculant shows significantly enhanced refining effect, reducing the grain size of pure aluminum to ∼110 μm. The refining mechanism is attributed to the combining effect of the cluster structure in submicron scale and the excellent crystallography matching relationship of CeB6 and Al. Mechanical properties of pure aluminum are also improved by addition of in situ CeB6/Al composite inoculant due to collaboration effect of dispersion strengthening and grain refining strengthening.

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