Enhanced emission from Eu(III) β-diketone complex combined with ether-type oxygen atoms of di-ureasil organic–inorganic hybrids

Abstract

Organic–inorganic hybrids, named di-ureasils and described by polyether-based chains grafted to both ends to a siliceous backbone through urea cross linkages, were used as hosts for incorporation of the well-known coordination complex of trivalent europium (Eu 3+) ions described by the formula [Eu(TTA) 3(H 2O) 2] (where TTA stands for thenoyltrifluoroacetone). By comparing with Eu 3+-doped di-ureasil without complex form the new materials prepared here enhanced the quantum efficiency for photoemission of Eu 3+ ions. The enhancement can be explained by the coordination ability of the organic counterpart of the host structure which is strong enough to displace water molecules in [Eu(TTA) 3(H 2O) 2] from the rare earth neighbourhood after the incorporation process. High intensity of Eu 3+ emission was observed with a low non-radiative decay rate under ultraviolet excitation. The quantum efficiency calculated from the decay of 5D 0 emission was 74%, which in the same range of values previously obtained for the most efficient Eu 3+ coordination compounds reported in literature. Luminescence, X-ray absorption and infrared absorption results considered together leads to a picture where the first coordination shell of Eu 3+ is composed of the 6 oxygen atoms of the 3 β-diketonate ligands and 2 ether-like oxygen atoms of the host.