Abstract
TiO2(B) anode for lithium-ion batteries is prepared by the hydrothermal method. The styrene butadiene rubber and sodium carboxyl methyl cellulose (SBR/CMC) and polyvinylidene fluoride (PVDF) binders are used to prepare the TiO2(B) electrodes. Scanning electron microscope and electrochemical impedance spectroscopy show that the electrode prepared with SBR/CMC has better electrode maintainability and electrochemical kinetics which result in better electrochemical performance. The optimized SBR/CMC binder content is proposed to be in the range of 12–15 wt%. In addition, the 1 M LiPF6 electrolyte dissolved in EC:DMC = 3:7 is more suitable for the TiO2(B) electrode. Using this suggested binder content and electrolyte, the TiO2(B) material exhibits superior capacity retention and rate capability. Even at the 10 C rate, the material still shows a discharge capacity of 142.5 mAh g−1 which keeps very well after 800 cycles. Based on this work, it is concluded that SBR/CMC is a promising binder for the TiO2(B) anode which provides not only better electrochemical performance but also more cheaper and environmental friendly than PVDF.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.