Enhanced dispersibility and dispersion stability of dodecylamine-protected silver nanoparticles by dodecanethiol for ink-jet conductive inks

Abstract

This work studied dodecylamine-protected silver nanoparticles modified by a small amount of dodecanethiol as the co-protective agent. Contents of the dodecanethiol and the protective agent capping on the surface of silver nanoparticles were analyzed using the method of oxygen flask combustion and a thermogravimetric analysis instrument. Results of electrical property determination and transmission electron microscopy indicate that certain amount of capping dodecanethiol can slow down the spontaneous sintering process of silver nanoparticles. When capping DDT content of silver nanoparticles is 1.70wt%, 10wt% suspensions are stable under −18°C and can be stored stably at room temperature as long as 120 days. Furthermore, the silver nanoparticle concentration could be increased to 20wt% with a stable storage time of 60 days at room temperature. Finally, stable polymer-free conductive inks with the silver nanoparticle concentration of 20wt% were produced to fabricate patterns by ink-jet printing. The resistivity of the PI-supported patterns having been annealed at 130°C for 10min is 7.2μΩcm.