Enhanced dielectric and mechanical properties of epoxy-cyanate ester resin by Al2O3 and OMMT

Abstract

In order to achieve the purpose of simultaneously improving the mechanical properties and dielectric properties of biscyanatophenylpropane (BCE), a copolymer of bisphenol A epoxy resin (E51) and (BCE) was used as the matrix resin (E51-BCE), and Al2O3 with sol–gel method and the organically montmorillonite (OMMT) were used as the reinforcements to prepare the Al2O3/OMMT/E51-BCE composites. The structure of Al2O3 was identified to be γ-Al2O3 by X-ray diffraction (XRD) and transmission electron microscope (TEM), and MMT was organically modified by intercalation agent octadecyl trimethyl ammonium chloride (OTAC) to obtain OMMT and characterized by Fourier-transform infrared spectrometer (FT-IR), thermogravimetric analysis (TGA) and scanning electron microscope (SEM). The results showed that the interlayer spacing of OMMT (2.14 nm) was bigger than that of MMT (1.44 nm), with an increase of about 48.6%. The results indicated that both Al2O3 and OMMT can improve the dielectric properties and mechanical properties of the composite materials. The Al2O3/OMMT/E51-BCE composites are found to have the best performance; the bending strength, bending modulus and impact strength were 187.34 MPa, 3.59 GPa and 35.12 kJ m−2, respectively, when the content of Al2O3 and OMMT are all 2 wt%. And the dielectric constant, dielectric loss tangent, breakdown strength and volume resistivity of the composites reached peak values of 3.4, 0.005, 19.53 kV mm−1 and 8.9 × 1014 Ω m, respectively. The overall performance of the composite fulfilled the basic requirements of electrical and insulating materials and could expand application of BCE material in many areas.