Enhanced corrosion resistance and in-vitro biodegradation of plasma electrolytic oxidation coatings prepared on AZ91 Mg alloy using ZnO nanoparticles-incorporated electrolyte

Abstract

MgO/ZnO composite coatings were successfully prepared on AZ91 Mg alloy by plasma electrolytic oxidation (PEO) method using electrolytes containing ZnO nanoparticles (NPs) to extend their biomedical applications. The effect of the concentration of 0 to 4.5 g·L−1 ZnO NPs in phosphate-based electrolyte on the microstructure, composition, physical features, corrosion and biodegradation properties of coatings was investigated. Observing the microstructure through field emission scanning electron microscopy (FESEM) confirmed that ZnO NPs were well up-taken in the coating structure with crater-like morphology and, they were mostly accumulated near the pores. As ZnO NPs concentration increased, more particles were incorporated in the coating; however, porosity, thickness and surface roughness reduced. The evaluation of the electrochemical behavior of specimens using potentiodynamic polarization test revealed that the polarization resistance of the samples increased from 9.26 to 683.2 kΩ·cm2 by adding 4.5 g·L−1 ZnO NPs. The study of corrosion mechanism by identifying the coating features using electrochemical impedance spectroscopy (EIS) indicated that the compacting of the coating and the difficulty of the penetration path of corrosive ions between the coating layers due to the presence of ZnO NPs had a more dominant effect relative to thickness reduction. Conducting the bioactivity test by immersion of coatings in simulated body fluid (SBF) solution for 14 days showed the higher growth of calcium phosphate layer formed on the sample as the concentration of ZnO NPs increases. In addition, the changes in weight loss and volume of hydrogen evolution were much less, and the mechanism of these changes was presented.