Abstract
Efficient removal of organic arsenic (roxarsone, ROX) from wastewater is highly demanded on the purpose of human health and environmental protection. This work aims to prepare Fe-N co-doped biochar (Fe-N-BC) via one-pot hydrothermal method using waste peanut shell, FeCl3·6H2O and urea, followed by pyrolysis. The effect of Fe-N co-doping on biochar's physicochemical properties, and adsorption performance for ROX were systematically investigated. At the pyrolysis temperature of 650 °C, Fe-N-BC-650 shows a significantly increased specific surface area of 358.53 m2/g with well-developed micro-mesoporous structure. Its adsorption capacity for ROX reaches as high as 197.32 mg/g at 25 °C, with > 90 % regeneration efficiency after multiple adsorption–desorption cycles. Correlation and spectral analysis revealed that the pore filling, π-π interactions, as well as hydrogen bonding play the dominant role in ROX adsorption. These results suggest that the Fe-N co-doped biochar shows great potential in the ROX removal from wastewater with high efficiency.
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