Enhanced Adsorption of Methyl Orange by Mongolian Montmorillonite after Aluminum Pillaring

Abstract

This article studies the enhancement of methyl orange (MO) adsorption by Mongolian montmorillonite (MMt) modified by the intercalation of the Keggin Al13 complex, followed by calcination during the pillaring process. The properties of MMt, Al-intercalated MMt (P-MMt), and Al-pillared MMt (P-MMt-C) were determined using X-ray diffraction (XRD), thermogravimetric analysis (TGA), surface-area analysis, and a field emission scanning electron microscope (FE-SEM). The MO adsorption by modified MMt was subsequently evaluated. The XRD basal distance (d001) and the specific surface area (SSA) increased after the modification of MMt. The TGA results revealed that P-MMt and P-MMt-C had better thermal stability than MMt. The Al-pillared MMt obtained after calcination (e.g., P-MMt-C400) showed a larger basal distance and surface area than that without pillaring. The MO adsorption process of P-MMt-C400 was supposed to be dominated by chemisorption and heterogeneous multilayer adsorption, according to the kinetic and isotherm studies. The maximum adsorption capacity of P-MMt-C400 is 6.23 mg/g. The MO adsorption ability of Al-pillared MMt was contributed by the Keggin Al13 complex attracting MO and the increase in the surface area of macro-, meso- and micro-pores (>1.2 nm). The Al-pillared MMt in this study could be applied as an adsorbent in a water purification system to remove MO or other dye elements.