Abstract
The study highlights the potential of Vetiveria Zizanioides derived biochar for heavy metal removal in multicomponent systems. Biochar efficiency varies with pH, metal ion concentration and residence time. Maximum removal efficiency was found to be 66.34, 67.23, 46.54, 69.92, 68.23 and 63.34% for Arsenic, Copper, Nickel, Cadmium, Lead and Chromium at 90 min respectively. Ternary system revealed that Copper ions have inhibitory effect on Lead ions and have lower adsorption capacity than binary system. Multicomponent isotherm model was used to analyse simultaneous adsorption of metal ions and shows a good fit with modified Langmuir model for binary and ternary systems. Fixed-bed column was tested for scale-up feasibility and maximum adsorption capacity of 139, 130, and 123 mg/g for Lead, Copper, and Nickel ions were obtained at 1.5 L/h and a bed height of 12 cm. In fixed bed column, multicomponent sequence provides more protection against premature exhaustion of biochar.
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