Abstract
Since humic substances (HSs) can cause environmental problems, their elimination has been attracting more and more concerns. In this study, we investigated HSs adsorption onto urea-derived graphitic carbon nitride (CNU) and elucidated adsorption mechanisms (i.e. heterogeneity, interface rearrangement, and multiple interactions). The adsorption capacity of CNUs was enhanced as increasing calcination temperature and time. Among CNUs, CNU-575–3 showed the highest adsorption capacity; the maximum adsorption capacities for humic acid (HA) and fulvic acid (FA) were 164.06 mg C/g, 14.61 L/cm·g, 91.12 mg C/g, and 5.34 L/cm·g, respectively. The adsorption affinity of CNUs mainly correlated with the amount of amino groups, and that of HSs components was dependent on aromaticity due to π-π interactions. More specifically, terrestrial humic-like and fulvic-like components within HA and FA showed the greatest adsorption affinity, respectively. HSs adsorption was remarkably affected by pH, alkali metals, and alkali earth metals via electrostatic interactions, H-bonding, cation bridge, and configurational effect. In addition, the adsorption of Elliott soil HA (ESHA) and the landfill leachate concentrate by CNUs was also highly efficient. This study shows the great promise of CNUs for HSs adsorption in waters and wastewaters.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
