Abstract

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Highlights

  • The bulk chemicals esters contribute to commo­ dity chemicals in nearly unlimited variety

  • Methyl acetate is used for the production of coatings, nitro-cellulose, cellulose acetate, cellulose ethers and celluloid, as well as for a variety of resins, plasticizers, lacquers and certain fats.[2]

  • Besides the synthesis of methyl acetate, this esterification reaction may potentially be applied in the recovery of dilute acetic acid from aqueous solutions.[3,4]

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Summary

Introduction

The bulk chemicals esters contribute to commo­ dity chemicals in nearly unlimited variety. Common fields of application include their use as solvents, plasticizers, surfactants, flavours, interm­ ediates in preparative organic chemistry, and many more.[1] Though well investigated, the technology of ester production offers some challenging characteristics regarding catalysis, operation conditions and downstream processing. The synthesis of methyl acetate (MeOAc) via liquid-phase esterification of acetic acid (HOAc) and methanol (MeOH) is a prominent example thereof. Methyl acetate is used for the production of coatings, nitro-cellulose, cellulose acetate, cellulose ethers and celluloid, as well as for a variety of resins, plasticizers, lacquers and certain fats.[2] Besides the synthesis of methyl acetate, this esterification reaction may potentially be applied in the recovery of dilute acetic acid from aqueous solutions.[3,4]

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