Abstract
This manuscript deal with the reaction of the 1-isothiocyanato six membered silatrane with different transition metal carbonyls. The adducts 1, 2, 3, 4 and 5 so formed were characterized by elemental analysis, infrared spectroscopy, 1H, 13C, 29Si NMR spectroscopy. η1-S bonding pattern was observed amongst the various coordination modes of the isothiocyanato group
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