Engineering of cation and anion vacancies in Co3O4 thin nanosheets by laser irradiation for more advancement of oxygen evolution reaction

Abstract

Atomic vacancy has been demonstrated to generate new energy states in the bandgap whereby providing more active sites in many electrocatalytic processes. In this work, a novel process is developed to yield both Co and O vacancies in the synthetical Co 3 O 4 nanosheets when subjected to a laser beam. The method, capable of creating both Co and O vacancies and embarking upon the prediction of the number of vacancies generated, is more reliable/controllable over other methods. The coupling of two types of vacancies eases the occurrence of Co 3 O 4 oxidation reaction at a very low overpotential, which then facilities the OER at an overpotential of 290 mV with a small Tafel slope of 76 mV dec −1 , much better than the pristine Co 3 O 4 and the benchmark RuO 2 . DFT calculations suggest that the induced multi- vacancies create trap state in the bandgap of Co 3 O 4 promoting the adsorption capability and advancing the water splitting. • Cation vacancies and anion vacancies were created by laser irradiation in Co 3 O 4 nanosheets. • The multi-vacancies along with porous structure are favorable for water adsorption and OER. • Advanced OER performance of Co 3 O 4 with both cobalt and oxygen vacancies. • An effective approach to maximizing the catalysis of the new or existing catalysts.