Energy transfer of Tb3+→Eu3+ in Ca2Al2SiO7 phosphors with multicolor tunable and optical temperature sensing properties

Abstract

Luminescent temperature sensors based on photoluminescent materials have received considerable attention for their advantages of quick and noninvasive measurement. In this paper, a series of Tb3+, Eu3+ single-doped and co-doped Ca2Al2SiO7 (CAS) phosphors were synthesized by sol-gel method. The phase purity, surface morphology, energy transfer, luminescence characteristics and temperature sensing properties of Tb3+, Eu3+ doped CAS phosphors have been studied carefully. Due to the energy transfer of Tb3+→Eu3+, CAS: Tb3+, Eu3+ phosphors demonstrate tunable luminescence under 238 nm excitation, in which the luminescence color gradually changes from purple-red to cool white, and then to warm white by continuously increasing the concentration of Tb3+ ions. The elongation of the fluorescence lifetime of Eu3+ with increasing Tb3+ ions content further confirms the energy transfer of Tb3+→Eu3+. The thermal behavior of CAS: Tb3+, Eu3+ phosphors shows enhanced luminescence intensity for 404 nm emission while suppressed luminescence intensity for 616 nm emissions with raising temperature, implying its potential in optical temperature sensing. Therefore, the temperature sensing performance is evaluated by using the fluorescence intensity ratio (I404 nm /I616 nm) in CAS: Tb3+, Eu3+ phosphors, showing a maximum relative sensitivity of 1.17%K−1 at 443 K. These results indicate that CAS: Tb3+, Eu3+ phosphors are promising candidates for tunable luminescence and non-contact temperature sensing.