Abstract
In the collision of Br + with Kr there is considerable transfer of translational to electronic energy and vice versa. This energy transfer is modelled as a Landau-Zener process at the points where the potential energy curves of the various electronic states of the halogen positive ion complex (KrBr +) cross. Experimental transitions among the spin-orbit states of Br + (viz. 1D 2 ⇌ 3P 0,1) are observed but all attempts to produce 1D 2 ⇌ 3P 2 have failed. Relativistic Cl calculations of lowlying states of KrBr + have been carried out to explain the above experimental observations.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
