Abstract
Product state distributions from charge-transfer collisions between Ar+–N2 and H+–O2 as well as collision-induced excitation involving N+2 on He, Ar, and Xe are presented. These data, obtained from collision-produced emission spectra, are compared with a Franck–Condon model for the excitation-radiation process; significant deviations are observed and explained on the basis of a qualitative curve-crossing model formulated to treat such vibronic excitation processes.
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