Energy Transfer from Pr3+ to Gd3+ and Upconversion Photoluminescence Properties of Y7O6F9:Pr3+, Gd3.

Abstract

Upconversion materials have numerous potential applications in light energy utilization due to their unique optical properties. The use of visible light excitation to obtain ultraviolet emission is a promising technology with broad application prospects, while relevant research is absent. A series of Pr3+, Gd3+ doped Y7O6F9 phosphors were synthesized by traditional solid-state reaction. X-ray diffraction, scanning electronic microscopy, steady-state photoluminescence spectra, a decay dynamic, and upconversion emission spectra of the samples were studied. Under the excitation of 238 nm, the energy transfer from Pr3+ to Gd3+ was realized and a strong ultraviolet B emission due to the 6P7/2→8S7/2 transition of the Gd3+ ions was achieved. Under the excitation of a 450 nm blue laser, Pr3+ absorbed two blue photons to realize the upconversion process and then transferred the energy to Gd3+ to obtain the ultraviolet B emission.