Abstract

Excited-state energy transfer from spherical green-light-emitting nanocrystals as donor to rod-shaped red-light-emitting nanocrystals as acceptor is shown to result in a predominant red fluorescence in mixed films. For this purpose red-light-emitting core-shell CdSe/CdS quantum rods with high fluorescence quantum yields of η F = 45 % were synthesized and used to create mixtures with green-light-emitting core-shell CdSe/CdS quantum dots (η F = 40%). For this donor-acceptor combination the Forster distance is less than 6.6 nm and close to the sum of the diameters of the dots and rods. Hence, only quantum dots directly neighboring a quantum rod can efficiently participate in the energy transfer. A simple rubbing technique was used to uniaxially align the quantum rods dispersed in thin films of quantum dots. Such mixed films showed polarized red emission, while the absorption remains unpolarized.

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