Abstract
We have examined the fluorescence characteristics of the garnet-type crystal Yb 3 Al 5 O 12 : Er 3+ (YbAlG : Er 3+ ) and studied the energy transfer process between the two rare earth ions over a temperature range 78–297 K. Certain data were compared with those of YAIG : Er 3+ . In YbAlG: Er 3+ , Yb fluorescence is observed at ≈1.03 μm (corresponding to the 2 F 5/2 → 2 F 7/2 transition); Er fluorescence occurs at ≈8500( 4 S 3/2 → 4 I 13/2 transition) and ≈1.6 μm ( 4 I 13/2 → 4 I 15/2 transition). In YA1G : Er 3+ , the same Er lines are observed with the addition of a band at ≈1 μ ( 4 I 11/2 → 4 I 15/2 transition). In YbAlG : Er 3+ , the decay pattern of the Yb emission is purely exponential at all the temperatures examined; the fluorescence lifetime ranges from 36 μ s (at 78 K) to 74 μs(at 269 K). The lifetime of the Er 4 I 13/2 level in the same sample increases from 5.4 ms (at 78 K) to 6.85 ms (at 294 K). The lifetime of this Er level in YAIG : Er 3+ is weakly temperature dependent over the same range with a value of ≈12 ms. Excitation spectra were obtained for the Er 1.53 μm fluorescence in YbAIG Er 3+ in order to verify the presence of Yb → Er energy transfer in this sample. The presence of the Yb absorption band (≈1 μm) in these spectra provides direct evidence of this energy transfer. The relative enhancement of this Yb band with respect to the Er bands in going from 78 K to 175 K is an indication of a more efficient transfer at the higher temperature. Excitation spectra obtained for the Yb 1.03 μm fluorescence in YbAIG : Er 3+ revealed the presence of Er → Yb energy transfer as well in this sample. The existence of both Yb → Er and Er → Yb transfer is expected, due to the resonance between the 4 I 11/2 → 4 I 15/2 transition of Er and the 2 F 5/2 → 2 F 7/2 transition of Yb. The above results are explained in terms of a rate equation model in which transfer in both directions is treated in the following manner: Yb → Er transfer is considered to be much more probable than decay processes originating at the Yb 2 F 5/2 level; Er → Yb transfer is treated as much more probable than decay processes originating at the Er 4 I 11/2 level.
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