(Energy Technology Division Graduate Student Award Address sponsored by Bio-Logic) Biomass-Derived Carbon Materials for Next-Generation Electrochemical Energy Storage Systems

Abstract

With rising energy concerns, efficient energy conversion and storage devices are urgently required to provide a sustainable, green energy supply. Electrochemical energy storage devices, such as supercapacitors and batteries, have been proven to be the most effective energy conversion and storage technologies for practical application. Currently, carbon materials hold the key for the development of high-performance electrochemical energy storage devices. However, the widely used carbon materials, such as graphite and activated carbon are often derived from non-renewable resources under relatively harsh environments, which hinders the sustainable development of electrochemical energy storage systems. In this context, biomass demonstrates many desired properties to derive renewable carbon materials for both electrochemical energy storage applications, because of its natural abundance and unlimited availability. Here, natural biomass, such as cotton textile, wheat flour, and corncobs, have been explored to produce renewable carbon materials via a low-cost and high throughput manufacturing process for energy storage systems design. Excitingly, the biomass-derived renewable activated carbon scaffolds not only demonstrated hierarchically porous structures but also excellent flexibility, making them ideal backbones for next-generation energy storage design. Specifically, activated cotton textile (ACT) with excellent flexibility and conductivity has been successfully derived from cotton textile for flexible energy storage systems design, such as flexible supercapacitors, flexible lithium-ion batteries, and flexible lithium-sulfur batteries. Besides flexible ACT, carbon nanotubes (CNTs) have also successfully derived from the natural yeast-fermented wheat dough without using any extra-catalysts or additional carbon sources. Yeast-derived carbon nanotubes from the fermented wheat dough not only provide an ideal sulfur host for lithium-sulfur batteries with a record lifespan of 1500 cycles but also expand our current understanding of the synthesis of carbon nanotubes. Biowastes-corncob, have also been explored to derive onion-like carbon materials for energy storage application. These research activities not only brought new insights on the deriving renewable carbon materials from natural abundant biomass resources but also boosted the design and fabrication of next-generation flexible energy-storage devices, which hold great promise for future wearable/flexible electronics.