Abstract

This study presents an analytical representation of the internal motion of a diatomic system using the improved Pöschl-Teller potential. The ro-vibrational energy spectrum is derived by solving the radial Schrödinger time independent wave equation (STIWE) under a 2D electromagnetic potential field. Additionally, an explicit equation for magnetic susceptibility is formulated from the internal partition function. The analytical models are used to investigate physical properties of CO (X1∑+), K2 (a3∑u+), BCl (X1∑+), and NaK (c3∑+) molecules. Average percentage absolute deviations (APAD) for the ro-vibrational energy spectrum are calculated as 0.1001 %, 0.5306 %, 1.2070 %, and 0.9779 %, respectively, compared to observed data. Numerical results are consistent with existing literature. Furthermore, the study reveals that the magnetic susceptibility of the system increases with temperature and decreases with an increase in magnetic field intensity, indicating its paramagnetic nature.

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