Abstract
The energy position and width of H levels in front of an Al surface are studied with the nonperturbative coupled angular mode (CAM) method. The results are compared with previously published results by Nordlander and Tully [Phys. Rev. Lett. 61 (1988) 990 and Surf. Sci. 211/212 (1988) 207]. A strong hybridization is observed inside the various manifolds. The angular distributions of ejected electrons associated with the hybrids of the n = 2 and 3 manifolds are analyzed and correlated with the size of the level widths.
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