Abstract
The trimethyltin undergo a very fast, reversible oxidative addition reaction with [PtMe2(Bu2bipy)], Bu2bipy = 4,4′-di-tert-butyl-2,2′-bipyridine, to give [PtXMe2(SnMe3)(Bu2bipy)] for which a complete energy profile can be obtained by using variable-temperature NMR methods; the reaction with X = I is the fastest known oxidative addition and activation energies when X = Cl suggest detailed structure for the transition state.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of the Chemical Society, Chemical Communications
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
