Abstract
A modification of the arrested relaxation infrared chemiluminescence technique has been used to study the energy disposal in two atom–radical reactions. Vinyl and formyl radicals were generated chemically and their subsequent reactions with O atoms (in the case of vinyl) and F atoms (in the case of formyl) were followed. Product CO emission was observed in the system O/C2H3. Emission from both CO and HF was seen in the F/HCO system. The O/C2H3 reaction gives rise to substantially higher excitation in the CO product than does the F/HCO case. In each case, bound intermediates may be formed; the differences in energy diposal are discussed in terms of the possible influence of these intermediates.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
