Abstract
A detailed parameter study is made of chemically active spherical bubbles. The calculations apply an up-to-date chemical mechanism for pure oxygen initial content, taking into account pressure dependency, duplication of chemical reactions, and proper third-body efficiency coefficients. The chemical yield is defined as the amount of substance at the maximum bubble radius, and the dissipated power is approached in a relatively new method. The parameter study focuses on finding the parameter combinations where maximum yield and maximum energy efficiency arise for various chemical species (O3, OH radical, H2 and H2O2). Results show that the locations of maximum yield and efficiency points differ significantly, depending on the chemical species. Usually, neither chemical yield nor efficiency values arise at maximum pressure amplitude and minimum driving frequency (as one would presumably expect).
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