Abstract
Energy-dependent electrospray ionization mass spectrometry (EDESI-MS) technique has been used for investigating the fragmentation of monomeric metal carbonyl complexes of general formula [M(CO) x (COOMe)] − (M = Cr, Fe, Mo, and W). The results show that in addition to the loss of CO, formaldehyde loss provides a pathway of fragmentation. Of all complexes investigated, the chromium complex exhibits the cleanest fragmentation. At very high voltages, the metal ions is either associated with a hydride or a methoxide ions.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
