Abstract
In recent years, it has been demonstrated that the energetic properties of many tetrazole-containing compounds can be enhanced through the formation of the corresponding N-oxides. The introduction of N-O groups increases the oxygen balance of tetrazole compounds, while providing additional coordination sites and enriching the coordination modes between tetrazole compounds and metal ions. The introduction of O atoms alters the polarity of the substance from N to N-O, the packing and density increase and therefore the detonation velocity (VD) and pressure (P) also increase. Based on this, energetic coordination polymers (ECPs) with tetrazole N-oxides serving as ligands possess extremely high research value. In this paper, we aim to summarize the existing ECPs based on tetrazole N-oxides briefly and discuss their advantages, emphasizing their excellent stability and application prospects.
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