Abstract

Diels-Alder reactions of the heteroaromatic diene furan proceed with enhanced isolated yields and reversal of endo/exo selectivity (2:1 endo vs exo) in the ionic liquids [bmim]BF 4 and [bmim]PF 6 compared to conventional methods. The potential utility of ionic liquids as solvents in Diels-Alder reactions of thiophene and pyrrole derivatives has also been demonstrated.

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