Abstract
The crystal structure of the most stable complex involving HgII co-ordinated to a macrocyclic tetrathia-ether (1,5,9,13-tetrathiacyclohexadecane) reveals that the HgII ion is situated almost in the centre of the four sulphur donor atoms, which themselves are twisted somewhat out of plane, with the inner co-ordination sphere being completed by two unequally bonded perchlorate ions situated along the z axis.
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More From: Journal of the Chemical Society, Chemical Communications
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