Abstract

The latent heat phase change materials (PCMs) have emerged as an important and effective thermal storage material. The massive change in volume and the requirement for specialized containment of PCMs limits the thermal storage application of the common PCM like paraffin wax. Herein, we report the encapsulation of paraffin wax with the cross-linked poly(styrene-divinylbenzene-acrylic acid) shell via suspension polymerization. The optical and SEM images of the prepared encapsulated phase change materials (EPCMs) were in the size range of 200–500 µm. The thermal charging-discharging rate of the EPCM was studied using a facile water bath technique. It was found that the optimized EPCM showed about 1.7 times faster-charging and 3.5 times faster discharging rate compared to reference PCM (without encapsulation). The latent heat for the EPCM was found to be about 3.3 times higher than the reference PCM. The thermal charging-discharging ability and latent heat values are higher for the encapsulated paraffin wax when compared with reference paraffin wax. The encapsulation of paraffin wax by polymeric materials via facial suspension polymerization using polymerizable vinyl monomers could find its application as heat storage materials.

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